5.NBT.A.3 asks children to read, write and compare decimals to thousandths. Placing 0.125 and 0.375 next to hundredths cards forces the comparison across place values, which is the comparison the standard names.
Some children will know 0.125 as one eighth. Encourage that link; it makes the placement a halving problem rather than a guess, which matters when only 0 is showing at first.
When to dropAfter two cards, drop 1 to fix the whole, then 0.5 to halve the line, then 0.25. The quarter marks make 0.125 an obvious halving once they are down.
Drop unlocks after 2 cards placed.
Ask which cards are also eighths, and write 0.125, 0.375 and 0.875 as eighths to close the loop.
Thousandths sit between the hundredths, and a decimal like 0.125 has an exact place you can find by halving.