3.NF.A.2 through the placement, and 3.NF.A.3.b through the 3/6 card landing on the 1/2 drop. The standard names 4/6 = 2/3 as an example of equivalence, and this line sets up that neighbourhood.
Thirds are harder to place than fourths because they do not sit on the halving points. Starting from 0 alone makes the early estimates rougher, and the disagreement that follows is good.
When to dropAfter two cards, drop 1 to fix the whole. Hold 1/2 as the final drop until 1/3 and 2/3 are placed, then drop it and check that 1/3 sits left of it, 2/3 sits right of it, and 3/6 lands right on it.
Drop unlocks after 2 cards placed.
Ask which was harder to place, thirds or fourths, and why the thirds feel more awkward.
Thirds and sixths share a line, sixths are half-steps of thirds, and 3/6 is 1/2 by another name.